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Unravelling the bottleneck of phosphonic acid anchoring groups aiming toward enhancing the stability and efficiency of mesoscopic solar cells

《化学科学与工程前沿（英文）》 2022年 第16卷 第7期   页码 1060-1078 doi: 10.1007/s11705-021-2117-z

摘要： Novel near-infrared sensitizers with different anchoring groups aiming toward improved stability and efficiency of dye-sensitized solar cells were synthesized. Adsorption of these dyes on the mesoporous TiO2 surface revealed the dye adsorption rate of –CH=CH–COOH (SQ-139)>–CH=C(CN)COOH (SQ-140)>–PO3H2 (SQ-143)>–CH=C(CN)PO3H2 (SQ-148)>–CH=C(CN)PO3H–C2H5 (SQ-157)>–PO3H–C2H5 (SQ-151)>–CH=CH–COOH(–PO3H2) (SQ-162). The binding strength of these dyes on mesoporous TiO2 as investigated by dye desorption studies follows SQ-162>SQ-143>SQ-148>SQ-139>SQ-157~SQ-151>SQ-140 order. The acrylic acid anchoring group was demonstrated to be an optimum functional group owing to its fast dye adsorption rate and better binding strength on TiO2 along with good photoconversion efficiency. Results of dye binding on TiO2 surface demonstrated that SQ-162 bearing double anchoring groups of phosphonic and acrylic acid exhibited>550 times stronger binding as compared to dye SQ-140 having cyanoacrylic acid anchoring group. SQ-140 exhibited the best photovoltaic performance with photon harvesting mainly in the far-red to near-infrared wavelength region having short circuit current density, open-circuit voltage and fill factor of 14.28 mA·cm–2, 0.64 V and 0.65, respectively, giving the power conversion efficiency of 5.95%. Thus, dye SQ-162 not only solved the problem of very poor efficiency of dye bearing only phosphonic acid while maintaining the extremely high binding strength opening the path for the design and development of novel near-infrared dyes with improved efficiency and stability by further increasing the π-conjugation.

关键词： anchoring groups     adsorption behaviour     dye-binding strength     squaraine dyes     dye-sensitized solar cells    

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ANN-based empirical modelling of pile behaviour under static compressive loading

Abdussamad ISMAIL

《结构与土木工程前沿（英文）》 2018年 第12卷 第4期   页码 594-608 doi: 10.1007/s11709-017-0446-2

摘要： Artificial neural networks have been widely used over the past two decades to successfully develop empirical models for a variety of geotechnical problems. In this paper, an empirical model based on the product-unit neural network (PUNN) is developed to predict the load-deformation behaviour of piles based SPT values of the supporting soil. Other parameters used as inputs include particle grading, pile geometry, method of installation as well as the elastic modulus of the pile material. The model is trained using full-scale pile loading tests data retrieved from FHWA deep foundations database. From the results obtained, it is observed that the proposed model gives a better simulation of pile load-deformation curves compared to the Fleming’s hyperbolic model and t-z approach.

关键词： piles in compression     load-deformation behaviour     product-unit neural network    

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Investigation of the hydro-mechanical behaviour of compacted expansive clay

Yujun CUI, An Ninh TA, Anh Minh TANG, Yingfa LU,

《结构与土木工程前沿（英文）》 2010年 第4卷 第2期   页码 154-164 doi: 10.1007/s11709-010-0019-0

摘要： The hydro-mechanical behaviour of compacted expansive Romainville clay was investigated. The soil was air-dried, crushed, and passed through a 2 mm sieve before being statically compacted to a dry density of 1.35 Mg/m. The mechanical behaviour was investigated by tests in oedometer with controlled suction using the vapor equilibrium technique (suction = 0, 9, 39, and 110 MPa). The vertical stress was applied in the range of 0–800 kPa. The experimental results are shown as follows: 1) wetting-induced swelling was higher at lower vertical stresses; 2) the vertical stress under which no swelling occurred during water flooding was estimated at 60 kPa, which can be considered as the swelling pressure of the soil tested; 3) the soil compressibility (changes of volume upon stress increases) was strongly influenced by the soil suction: the lower the suction, the higher the compressibility. The hydraulic behaviour was investigated using a large-scale infiltration chamber (800 mm × 1000 mm in section and 1000 mm high). The large size of the soil column allowed burying the volumetric water content sensors (ThetaProbe) without significantly affecting the water transfer and the soil swelling during infiltration. The soil suction was monitored along the soil height (every 100 mm) using various relative humidity sensors and psychrometers. In the infiltration test, water was kept on the soil surface and changes in suction and volumetric water content were monitored for 338 d. The wetting front has reached the bottom of the soil column at the end of the test. The data from the simultaneous monitoring of suction and water content were used to determine the water retention curve and the unsaturated hydraulic conductivity using the instantaneous profile method. It has been observed that the soil water retention curve depends on the soil depth; that is to be related to the soil depth-dependent swelling. The unsaturated hydraulic conductivity was found to be quite low, comprised between 3 × 10 m/s (at saturated state) and 10 m/s (at about 100 MPa suction).

关键词： Romainville clay     suction control     oedometer test     large infiltration task     hydro-mechanical behaviour    

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Nonlinear dynamic behaviour of a cam mechanism with oscillating roller follower in presence of profile

Walha LASSAAD, Tounsi MOHAMED, Driss YASSINE, Chaari FAKHER, Fakhfakh TAHER, Haddar MOHAMED

《机械工程前沿（英文）》 2013年 第8卷 第2期   页码 127-136 doi: 10.1007/s11465-013-0254-x

摘要：

In this paper we investigate the nonlinear dynamic behaviour of a cam mechanism with oscillating roller follower in presence of defects. The nonlinear developed lumped-mass model includes eight degrees of freedom with two nonlinear hertzian contacts. The first one is located between cam and first roller while the second is between second roller and the sliding rod. The nonlinear dynamic behaviour is described by second order differential equations which are resolved by using the implicit Newmark algorithm combined with the Newton-Raphson iterative scheme. The influence of the cam profile error on the dynamic behaviour is also investigated.

关键词： cam     nonlinear behaviour     oscillating roller follower     profile error    

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Bending and rotational behaviour of semi-continuous composite beams

WANG Jingfeng, LI Guoqiang

《结构与土木工程前沿（英文）》 2008年 第2卷 第2期   页码 116-122 doi: 10.1007/s11709-008-0015-9

摘要： Stresses and deflections were measured in various semi-continuous composite beams. The bending and rotational capacities of the composite connections were measured in terms of beam curvatures and deflections by using two full-scale semi-rigid composite frames with monotonic loadings. The effect of semi-rigid connections on the performance of composite beams with various loadings was compared with predictions and codes. The tests show that the semi-continuous composite beams are more economic and effective than the simple or continuous composite beams. The semi-rigid connections affect the bending capacities and beam deflections, so the connection behavior should be considered in the design of composite beams. Yielding analysis of the steel beam bottom flange has some influence on the deflection calculation of composite beams.

关键词： rotational     effective     deflection calculation     semi-continuous composite     full-scale semi-rigid    

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Effect of embedment length of untreated natural fibres on the bond behaviour in cement mortar

Gudimella RAMAKRISHNA, Sriraman PRIYADHARSHINI

《结构与土木工程前沿（英文）》 2018年 第12卷 第4期   页码 454-460 doi: 10.1007/s11709-017-0454-2

摘要： The present investigation is focused on studying the effects of various matrices with 1:3, 1:4 and 1:5 mortars and fibre types of sisal and coir on the bond behavior at various ages of curing, i.e., 24 h, 3 d, 7 d and 28 d. The other parameters included in the investigation are water/cement (w/c) ratio, sand gradation and embedment length of fibres. In addition, the type of failure of sisal and coir fibres for different mixes of mortars at various curing ages is also reported. From the results, it is seen that the bond strength is improving with respect to age of curing in case of sisal fibres, but decreases in case of coir fibres. The failure of fibres due to fibre fracture is observed in sisal fibres and fibre pullout is observed in coir fibres. The other varying parameters such as mortar mixes, sand gradation, w/c ratio and embedded length also showed significant effect on bond behaviour of sisal and coir fibre with the cement mortar mixes.

关键词： bond strength     cement mortar     natural fibre     pullout test     type of failure    

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从原子结构探讨贵金属在提取冶金过程中的行为

陈景

《中国工程科学》 1999年 第1卷 第2期   页码 34-40

摘要：

从原子结构特征分析了第Ⅷ族和IB族中Fe、Co、Ni、Cu 3d贱金属元素与其余8个贵金属元素化学性质的差异，以及Ru、Rh、Pd、Ag 4d贵金属与Os、Ir、Pt、Au 5d贵金属化学性质的差异。指出横向比较时，它们的化学稳定性都是从左到右增大；纵向比较时，化学稳定性是3d≤4d＜5d。以从硫化铜镍矿中提取富集贵金属为例，讨论了焙烧-还原熔炼-氧化吹炼等火法过程及电解富集、阳极泥硫酸化处理、湿法氯化、加压氧化、选择性还原等湿法过程中贵金属的行为。

关键词： 原子结构     贵金属     提取冶金    

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Contributions of adsorption, bioreduction and desorption to uranium immobilization by extracellular polymeric

《环境科学与工程前沿（英文）》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1707-z

摘要：

● EPS immobilizes U(VI) via adsorption, bioreduction and desorption.

关键词： Adsorption     Bioreduction     Desorption     Kinetics     Isotherm     Uranium    

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Polypropylene microplastics alter the cadmium adsorption capacity on different soil solid fractions

《环境科学与工程前沿（英文）》 2022年 第16卷 第1期   页码 3-3 doi: 10.1007/s11783-021-1437-z

摘要：

Microplastics (MPs) are widely present in a variety of environmental media and have attracted more and more attention worldwide. However, the effect of MPs on the interaction between heavy metals and soil, especially in soil solid fraction level, is not well understood. In this study, batch experiments were performed to investigate the adsorption characteristics of Cd in bulk soil and three soil solid fractions (i.e. particulate organo matter (POM), organic-mineral compounds (OMC), and mineral) with or without polypropylene (PP) MPs.

关键词： Polypropylene microplastics     Cadmium     Adsorption     POM     OMC     Mineral    

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Cesium removal from radioactive wastewater by adsorption and membrane technology

《环境科学与工程前沿（英文）》 2023年 第18卷 第3期 doi: 10.1007/s11783-024-1798-1

摘要：

● Removal of cesium from radioactive wastewater is still a challenging.

关键词： Cesium     Adsorption     Membrane separation     Advanced liquid processing system     Fukushima nuclear accident    

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Dual-functional sites for synergistic adsorption of Cr(VI) and Sb(V) by polyaniline-TiO hydrate: Adsorption

《环境科学与工程前沿（英文）》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1526-7

摘要：

• PANI/Ti(OH)n(4–n)+ exhibited excellent adsorption capacity and reusability.

关键词： Polyaniline/TiO2     Chromium     Antimony     Adsorption     Desorption     Mechanism    

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Kinetics and thermodynamics of the phosphine adsorption on the modified activated carbon

Bingnan REN

《化学科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 203-208 doi: 10.1007/s11705-010-0571-0

摘要： The kinetics and the thermodynamics of phosphine (PH ) adsorption on the modified activated carbon have been explained for the adsorption process of PH . This study investigated the kinetic and thermodynamic properties of PH adsorption on the activated carbon impregnated with 5% HCl solution. The thermodynamic properties including PH adsorption isotherm and adsorption heat were separately investigated at 20°C, 70°C, 90°C. The results showed that the Freundlich-type isotherm equation described the isotherms well. The adsorption capacity increased with increasing temperature between 20°C and 70°C. Between 70°C and 90°C, the adsorption capacity decreased obviously with increasing temperature. The adsorption capacity reached the maximum at 70°C. By analyzing the results of the kinetics and the thermodynamics, we found that the adsorption of PH was dominated by physical adsorption at the lower temperature (20°C). Then with increasing temperature, chemical adsorption gradually dominated in the adsorption process. The adsorption capacity decreased at above 70°C is due to the exothermic effects in the process of adsorption.

关键词： adsorption     PH3     activated carbon     kinetics     thermodynamics    

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An adsorption study of

Lingxiao FU, Jianhua ZU, Enxi GU, Huan WANG, Linfeng HE

《能源前沿（英文）》 2020年 第14卷 第1期   页码 11-17 doi: 10.1007/s11708-019-0634-y

摘要： Nanoscale zero-valent iron (nZVI) supported on D001 resin (D001-nZVI) was synthesized for adsorption of high solubility and mobility radionuclide Tc. Re(VII), a chemical substitute for Tc, was utilized in batch experiments to investigate the feasibility and adsorption mechanism toward Tc(VII). Factors (pH, resin dose) affecting Re(VII) adsorption were studied. The high adsorption efficiency of Re(VII) at pH= 3 and the solid-liquid ratio of 20 g/L. X-ray diffraction patterns revealed the reduction of into ReO immobilized in D001-nZVI. Based on the optimum conditions of Re(VII) adsorption, the removal experiments of Tc(VII) were conducted where the adsorption efficiency of Tc(VII) can reach 94%. Column experiments showed that the Thomas model gave a good fit to the adsorption process of Re(VII) and the maximum dynamic adsorption capacity was 0.2910 mg/g.

关键词： technetium     nanoscale zero-valent iron (nZVI)     D001 resin     adsorption    

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Parameter studies on impact in a lap joint

Amir M. RAHMANI,Elizabeth K. ERVIN

《机械工程前沿（英文）》 2015年 第10卷 第1期   页码 64-77 doi: 10.1007/s11465-014-0322-x

摘要：

To represent a loose lap joint, a beam impacting four springs with gaps is modeled. Modal analysis with base excitation is solved, and time histories of contact points are closely monitored. Using the impulse during steady state response, six influential parameters are studied: damping ratio, contact stiffness, intermediate contact position, gap, excitation amplitude and beam height. For all parameters, the system response is highly controlled by modes with two contacting springs. Each parameter’s effect on system response is presented including unstable regions, unique trend behaviours result. Recommendations for structural designers are also noted.

关键词： impact mechanics     contact     joint behaviour     modal analysis     parameter study    

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Behaviour of self-centring shear walls——A state of the art review

《结构与土木工程前沿（英文）》 2023年 第17卷 第1期   页码 53-77 doi: 10.1007/s11709-022-0850-0

摘要： The application of unbonded post-tensioning (PT) in structural walls has led to the development of advanced self-centring (rocking) shear wall systems that has significant advantages, including accelerated construction due to the incorporation of prefabricated elements and segmental construction for different materials (e.g., concrete, masonry, and timber), reduced residual drifts, and little damage upon extreme seismic and wind loads. Concrete, masonry, and timber are often used for the construction of unbonded PT structural wall systems. Despite extensive research since the 1980s, there are no well-established design guidelines available on the shear wall configuration with the required energy dissipation system, joint’s locations and acceptance criteria for shear sliding, confinement, seismic performance factors, PT loss, PT force range and residual drifts of shear walls subjected to lateral loads. In this research a comprehensive state-of-the-art literature review was performed on self-centring shear wall system. An extensive study was carried out to collect a database of 100 concrete, masonry, and self-centring shear wall tests from the literature. The established database was then used to review shear walls’ configurations, material, and components to benchmark requirements applicable for design purposes. The behaviour of concrete, masonry and timber shear walls were compared and critically analysed. The general behaviour, force-displacement performance of the walls, ductility, and seismic response factors, were critically reviewed and analysed for different self-centring wall systems to understand the effect of different parameters including configurations of the walls, material used for construction of the wall (concrete, masonry, timber) and axial stress ratio. The outcome of this research can be used to better understand the behaviour of self-centring wall system in order to develop design guidelines for such walls.

关键词： self-centring shear walls     rocking walls     energy dissipation     seismic performance factors     PT loss     residual drift    

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标题 作者 时间 类型 操作

Unravelling the bottleneck of phosphonic acid anchoring groups aiming toward enhancing the stability and efficiency of mesoscopic solar cells

期刊论文

ANN-based empirical modelling of pile behaviour under static compressive loading

Abdussamad ISMAIL

期刊论文

Investigation of the hydro-mechanical behaviour of compacted expansive clay

Yujun CUI, An Ninh TA, Anh Minh TANG, Yingfa LU,

期刊论文

Nonlinear dynamic behaviour of a cam mechanism with oscillating roller follower in presence of profile

Walha LASSAAD, Tounsi MOHAMED, Driss YASSINE, Chaari FAKHER, Fakhfakh TAHER, Haddar MOHAMED

期刊论文

Bending and rotational behaviour of semi-continuous composite beams

WANG Jingfeng, LI Guoqiang

期刊论文

Effect of embedment length of untreated natural fibres on the bond behaviour in cement mortar

Gudimella RAMAKRISHNA, Sriraman PRIYADHARSHINI

期刊论文

从原子结构探讨贵金属在提取冶金过程中的行为

陈景

期刊论文

Contributions of adsorption, bioreduction and desorption to uranium immobilization by extracellular polymeric

期刊论文

Polypropylene microplastics alter the cadmium adsorption capacity on different soil solid fractions

期刊论文

Cesium removal from radioactive wastewater by adsorption and membrane technology

期刊论文

Dual-functional sites for synergistic adsorption of Cr(VI) and Sb(V) by polyaniline-TiO hydrate: Adsorption

期刊论文

Kinetics and thermodynamics of the phosphine adsorption on the modified activated carbon

Bingnan REN

期刊论文

An adsorption study of

Lingxiao FU, Jianhua ZU, Enxi GU, Huan WANG, Linfeng HE

期刊论文

Parameter studies on impact in a lap joint

Amir M. RAHMANI,Elizabeth K. ERVIN

期刊论文

Behaviour of self-centring shear walls——A state of the art review

期刊论文